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 TechNeed Challenge

Seeking: Methods of attaching/grafting linear alpha-olefins onto PE, polyester elastomers, fluoros, and other polymers

Seeking methods of grafting alpha-olefins. Image (c) Microsoft Inc.

Our client needs to functionalize polymers by grafting a linear aliphatic olefin to the polymer backbone. The polymers we’re working with include harder-to-functionalize materials — in particular polyethylene, fluoropolymers, and thermoplastic polyester elastomers (such as DuPont Hytrel®).

Our polymer applications often require high temperature resistance and high materials performance. Often, our polymers must perform at 150 degrees C, or even up to 280 C as in the case of polyethylenes.

We are particularly interested in grafting an aliphatic alpha-olefin to a thermoplastic polyester elastomer. The terminal double bond functional group must be retained in the final polymer.

There are several constraints on the solution technology:

  • A dendromeric olefin would prohibit other processing we need to perform on the material.
  • General high-temperature stability.
  • Prefer no other functional group within six carbons of the olefin, but this is not a requirement.
  • Prefer solutions that can generalize across polymers, but this also is not a requirement.

Although we may wish to manufacture small batches, ideally, we’d be able to purchase the olefin-grafted polymer from a secondary company that makes the material for us.

The olefin-containing polymer will be compounded into a formulation that will be made into components such as connectors, housings, and other moldable parts. This technology will allow for the formation of a more durable polymer in a secondary processing step, e.g. higher use temperature, abrasion resistance, increased stiffness.

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Want to see more? TechNeeds are anonymous requests for technology. The TechNeed Challenge periodically highlights TechNeeds that you and your organization may be able to meet. Click View Listing Details to see the complete TechNeed -- even if you're not already a member.

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