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High-Yield Production of Ortho-Nitro Aromatic Acids by Oxidation of Ortho-Nitroalkylaromatic Compounds
This technology provides a safe, environmentally acceptable, and economically attractive process for the production of ortho-nitroaromatic acids in high yield from ortho-nitroalkylaromatic compounds. The improved process comprises direct oxidation of ortho-nitroaromatic compounds in an oxidation-resistant solvent, with a catalytic metal salt in air in the presence of an aldehyde or ketone. These compounds are used as corrosion inhibitors and as intermediates in the production of dyes, pharmaceuticals, agrochemicals, pigments, perfumes, and flavors.ortho-nitroalkylaromatic compounds (ONAC) oxidized corresponding ortho-nitroaromatic acids (ONAA)

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